CAS 406681-09-2 (S)-Me-Bophoz - Catalysts / Alfa Chemistry

Synonyms

(S)-N-Methyl-N-diphenylphosphino-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine, (1S)-1-(Diphenylphosphino)-2-[(1S)-1-[(diphenylphosphino)methylamino]ethyl]ferrocene, Methyl-BoPhoz

Molecular Weight

611.5

Molecular Formula

C37H35Fe NP2

Canonical SMILES

[Fe].[CH]1[CH][CH][CH][CH]1.C[C@@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)N(C)P(c5ccccc5)c6ccccc6

InChI

1S/C32H30NP2.C5H5.Fe/c1-26(33(2)35(29-20-11-5-12-21-29)30-22-13-6-14-23-30)31-24-15-25-32(31)34(27-16-7-3-8-17-27)28-18-9-4-10-19-28;1-2-4-5-3-1;/h3-26H,1-2H3;1-5H;/t26-;;/m1../s1

InChI Key

ZIAZHUWEJYUGEO-FBHGDYMESA-N

Melting Point

104.1-109.2 °C

MSDS

Download MSDS

COA

Download COA

Spec Sheet

Download Spec Sheet

Application

Methyl-BoPhoz can be used:
As an efficient ligand for asymmetric hydrogenation reactions.
To synthesize a single enantiomer of cyclopropylalanine via hydrogenation reaction using rhodium catalyst.
To prepare chiral phenylalanine derivatives from α-amido cinnamic acids (or esters) using rhodium catalyst.