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(R)-Xyl-PPhos

Catalog Number
ACM442905331-1
Product Name
(R)-Xyl-PPhos
Structure
(R)-Xyl-PPhos
CAS
442905-33-1
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Synonyms
(R)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine
Molecular Weight
756.85
Molecular Formula
C46H50N2O4P2
Canonical SMILES
COc1cc(P(c2cc(C)cc(C)c2)c3cc(C)cc(C)c3)c(c(OC)n1)-c4c(OC)nc(OC)cc4P(c5cc(C)cc(C)c5)c6cc(C)cc(C)c6
InChI
1S/C46H50N2O4P2/c1-27-13-28(2)18-35(17-27)53(36-19-29(3)14-30(4)20-36)39-25-41(49-9)47-45(51-11)43(39)44-40(26-42(50-10)48-46(44)52-12)54(37-21-31(5)15-32(6)22-37)38-23-33(7)16-34(8)24-38/h13-26H,1-12H3
InChI Key
JRTHAKOHBMETRC-UHFFFAOYSA-N
Melting Point
190-194 °C
Assay
0.97
Optical Activity
[α]20/D +125°, c = 1 in chloroform
Application
Ligand employed in the asymmetic hydrogenation of ß-keto esters, 2-arylacrylates, aryl ketones , and other substrates.
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