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(R)-Me-Bophoz

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Catalog Number

ACM406680942-1

Product Name

(R)-Me-Bophoz

Structure

CAS

406680-94-2

Product Overview
Usage

Synonyms

(R)-N-Methyl-N-diphenylphosphino-1-[(S)-2-diphenylphosphino)ferrocenyl]ethylamine, (1R)-1-(Diphenylphosphino)-2-[(1R)-1-[(diphenylphosphino)methylamino]ethyl]ferrocene, Methyl-BoPhoz

Molecular Weight

611.5

Molecular Formula

C37H35Fe NP2

Canonical SMILES

[Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)N(C)P(c5ccccc5)c6ccccc6

InChI

1S/C32H30NP2.C5H5.Fe/c1-26(33(2)35(29-20-11-5-12-21-29)30-22-13-6-14-23-30)31-24-15-25-32(31)34(27-16-7-3-8-17-27)28-18-9-4-10-19-28;1-2-4-5-3-1;/h3-26H,1-2H3;1-5H;/t26-;;/m1../s1

InChI Key

ZIAZHUWEJYUGEO-FBHGDYMESA-N

Melting Point

108.7-113.6 °C

Assay

≥96%

Application

(R)-Me-Bophoz serves as a highly efficient ligand for asymmetric hydrogenation processes. It plays a critical role in Rhodium-catalyzed asymmetric hydrogenation of dehydro-α-amino acid derivatives, as well as itaconate derivatives, facilitating significant transformations in these compounds. Additionally, (R)-Me-Bophoz is utilized in Iridium-catalyzed asymmetric hydrogenation, contributing to the synthesis of an αvβ3 integrin antagonist intermediate. Moreover, it is instrumental in the Rhodium-catalyzed asymmetric hydrogenation of β-amino-vinylphosphonates, converting them into β-aminophosphonates with high specificity and efficiency.

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