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(R)-Me-Bophoz

Catalog Number
ACM406680942-1
Product Name
(R)-Me-Bophoz
Structure
(R)-Me-Bophoz
CAS
406680-94-2
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Synonyms
(R)-N-Methyl-N-diphenylphosphino-1-[(S)-2-diphenylphosphino)ferrocenyl]ethylamine, (1R)-1-(Diphenylphosphino)-2-[(1R)-1-[(diphenylphosphino)methylamino]ethyl]ferrocene, Methyl-BoPhoz
Molecular Weight
611.5
Molecular Formula
C37H35Fe NP2
InChI
1S/C32H30NP2.C5H5.Fe/c1-26(33(2)35(29-20-11-5-12-21-29)30-22-13-6-14-23-30)31-24-15-25-32(31)34(27-16-7-3-8-17-27)28-18-9-4-10-19-28;1-2-4-5-3-1;/h3-26H,1-2H3;1-5H;/t26-;;/m1../s1
InChI Key
ZIAZHUWEJYUGEO-FBHGDYMESA-N
Melting Point
108.7-113.6 °C
Assay
≥96%
Application
Efficient ligand for asymmetric hydrogenation
(R)-N-Methyl-N-diphenylphosphino-1-[(S)-2-diphenylphosphino)ferrocenyl]ethylamine-rhodium complex can efficiently catalyze the asymmetric hydrogenation of 2-tert-butoxycarbonylamino-3-cyclopropylacrylic acid benzyl ester to form (S)-2-tert-butoxycarbonylamino-3-cyclopropylpropionic acid benzyl ester.
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