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(S)-Me-Bophoz

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Catalog Number

ACM406681092-1

Product Name

(S)-Me-Bophoz

Structure

CAS

406681-09-2

Product Overview
Usage

Synonyms

(S)-N-Methyl-N-diphenylphosphino-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine, (1S)-1-(Diphenylphosphino)-2-[(1S)-1-[(diphenylphosphino)methylamino]ethyl]ferrocene, Methyl-BoPhoz

Molecular Weight

611.5

Molecular Formula

C37H35Fe NP2

Canonical SMILES

[Fe].[CH]1[CH][CH][CH][CH]1.C[C@@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)N(C)P(c5ccccc5)c6ccccc6

InChI

1S/C32H30NP2.C5H5.Fe/c1-26(33(2)35(29-20-11-5-12-21-29)30-22-13-6-14-23-30)31-24-15-25-32(31)34(27-16-7-3-8-17-27)28-18-9-4-10-19-28;1-2-4-5-3-1;/h3-26H,1-2H3;1-5H;/t26-;;/m1../s1

InChI Key

ZIAZHUWEJYUGEO-FBHGDYMESA-N

Melting Point

104.1-109.2 °C

Application

(S)-Me-Bophoz is a yellow to orange amorphous solid designed to serve as a highly effective ligand in various asymmetric hydrogenation reactions. Its primary purpose is to facilitate the synthesis of single enantiomers, such as cyclopropylalanine, from hydrogenation reactions utilizing rhodium catalysts. Additionally, it is instrumental in preparing chiral phenylalanine derivatives from α-amido cinnamic acids or esters, again employing rhodium catalysts. The product is also key in the rhodium-catalyzed asymmetric hydrogenation of β-amido-vinylphosphonates and finds use in the rhodium or iridium-catalyzed asymmetric hydrogenation of α,β-unsaturated esters, making it a versatile tool in creating enantiomerically enriched compounds.

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406681-09-2
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