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(Diacetoxyiodo)benzene

Catalog Number
ACM3240344
Product Name
(Diacetoxyiodo)benzene
Structure
(Diacetoxyiodo)benzene
CAS
3240-34-4
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Synonyms
CS-W011998; ST24032066; Phenyliodine diacetate; Iodine, bis(acetato-O)phenyl- (9CI); PIDA; bis(acetyloxy)(phenyl)-lambda~3~-iodane; Phenyliodine(III) diacetate; (acetyloxy)(phenyl)- -iodanyl acetate; Phenyliodo diacetate; 240I344;
IUPAC Name
[acetyloxy(phenyl)-λ3-iodanyl] acetate;
Molecular Weight
322.098g/mol
Molecular Formula
C10H11IO4;
InChI
InChI=1S/C10H11IO4/c1-8(12)14-11(15-9(2)13)10-6-4-3-5-7-10/h3-7H,1-2H3;
InChI Key
ZBIKORITPGTTGI-UHFFFAOYSA-N;
Storage
-20°C
Complexity
220
Covalently-Bonded Unit Count
1
EC Number
221-808-1
Exact Mass
321.97g/mol
H-Bond Acceptor
4
Heavy Atom Count
15
Monoisotopic Mass
321.97g/mol
NSC Number
226375
Rotatable Bond Count
5
Topological Polar Surface Area
52.6A^2
Application
(Diacetoxyiodo)benzene is a hypervalent iodine reagent that is used in conjunction with catalytic amount of sodium azide in acetonitrile, which enables oxidative decarboxylation of 2-aryl carboxylic a

cid into the corresponding aldehydes, ketones and nitriles.
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