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Carbonyl(dihydrido)tris(triphenylphosphine)ruthenium(II)

Catalog Number
ACM25360321
Product Name
Carbonyl(dihydrido)tris(triphenylphosphine)ruthenium(II)
Structure
Carbonyl(dihydrido)tris(triphenylphosphine)ruthenium(II)
CAS
25360-32-1
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Synonyms
25360-32-1;Carbonyl(dihydrido)tris(triphenylphosphine)ruthenium(II);Carbonyldihydridotris(triphenylphosphine)ruthenium(II);Dihydridocarbonyltris(triphenylphosphine)ruthenium;C55H47OP3Ru;[(C6H5)3P]3Ru(CO)H2;AKOS024258165;Carbonyl(dihydrido)tris(triphenylphosphine)ruthenium (II);
IUPAC Name
formaldehyde;ruthenium dihydride;triphenylphosphane;
Molecular Weight
919.987g/mol
Molecular Formula
C55H49OP3Ru;
InChI
InChI=1S/3C18H15P.CH₂O.Ru.2H/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;;/h3*1-15H;1H2;;;;
InChI Key
CEEYDFHDINQLNF-UHFFFAOYSA-N;
Storage
Refrigerator
Complexity
204
Covalently-Bonded Unit Count
5
Exact Mass
920.204g/mol
H-Bond Acceptor
1
Heavy Atom Count
60
Monoisotopic Mass
920.204g/mol
Rotatable Bond Count
9
Topological Polar Surface Area
17.1A^2
Application
Catalyst for the arylation (or alkenylation) of anthraquinone and PBI.

Catalytic C-C bond formation.

Transfer hydrogenative coupling of isoprene to alcohols or aldehydes.

Alkanes (and alkenes) from alcohols by tandem hydrogen transfer and condensation.

Catalyst for the conversion of primary alcohols and aldehydes into methyl esters.

Precatalyst for hydrogen production by means of alcohol dehydrogenation.
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