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Carbonylhydridotris(triphenylphosphine)iridium(I)

Catalog Number
ACM17250258-1
Product Name
Carbonylhydridotris(triphenylphosphine)iridium(I)
Structure
Carbonylhydridotris(triphenylphosphine)iridium(I)
CAS
17250-25-8
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Synonyms
Carbon monoxide;iridium;triphenylphosphane
IUPAC Name
carbon monoxide;iridium;triphenylphosphane;
Molecular Weight
1007.1
Molecular Formula
C55H45IrOP3
InChI
InChI=1S/3C18H15P.CO.Ir/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;/h3*1-15H;
InChI Key
OWVGPTPQWABNND-UHFFFAOYSA-N
Melting Point
170 °C
Purity
99%
Appearance
Powder
Complexity
212
Covalently-Bonded Unit Count
5
EC Number
241-282-7
Exact Mass
1007.23125
H-Bond Acceptor
1
Heavy Atom Count
60
Monoisotopic Mass
1007.23125
Rotatable Bond Count
9
Topological Polar Surface Area
1 Ų
Application
Catalyst for ring-opening isomerization of unsymmetrically substituted methylenecyclopropanes into 1,3-dienes

Catalyst for asymmetric transfer hydrogenation of aromatic ketones under base-free conditions

Catalyst for C-F bond activation for the C-S cross-coupling of aryl fluorides with diaryl disulfides to synthesize thioethers.
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