NAVIGATION

Tel:
Fax:
Address:
Email: For product inquiries or a copy of our product catalog, please use our online system or send an email to .

Tri-3,5-xylylphosphine

PRICE INQUIRY

Catalog Number

ACM69227470-2

Product Name

Structure

CAS

69227-47-0

Product Overview
Usage

Synonyms

Phosphine, tris(3,5-dimethylphenyl)-; Tris(3,5-dimethylphenyl)phosphine, 96%; AN-37902; CTK8C5349; MFCD03094579; TC-164724; ZINC59439992; 69227-47-0; FT-0655401; 227T470;

IUPAC Name

tris(3,5-dimethylphenyl)phosphane;

Molecular Weight

346.454g/mol

Molecular Formula

C24H27P;

Canonical SMILES

CC1=CC(=CC(=C1)P(C2=CC(=CC(=C2)C)C)C3=CC(=CC(=C3)C)C)C;

InChI

InChI=1S/C24H27P/c1-16-7-17(2)11-22(10-16)25(23-12-18(3)8-19(4)13-23)24-14-20(5)9-21(6)15-24/h7-15H,1-6H3;

InChI Key

XRALRSQLQXKXKP-UHFFFAOYSA-N;

Complexity

327

Covalently-Bonded Unit Count

Exact Mass

346.185g/mol

Heavy Atom Count

Monoisotopic Mass

346.185g/mol

Rotatable Bond Count

Topological Polar Surface Area

0A^2

Application

Tri-3,5-xylylphosphine serves as a versatile catalyst, primarily in the realm of organic synthesis. It is instrumental in advancing Cu/diphosphine-catalyzed asymmetric hydrogenation of heteroaromatic ketones and enones, and facilitates highly selective rhodium-catalyzed hydrogenation reactions. Its utility extends to the field of silicon-stereogenic silanaphthalenes, where it aids in both classical and kinetic resolution processes. Additionally, Tri-3,5-xylylphosphine plays a crucial role in the kinetic resolution of donor-functionalized secondary alcohols, achieved via Cu-H-catalyzed stereoselective silylation through dehydrogenative Si-O coupling with Si-stereogenic silanes. Furthermore, it is employed in comparative studies examining the conformational rigidity of silicon-stereogenic silanes within asymmetric catalysis.

If you have any other questions or need other size, please get a quote.

CAS
Size
Purity
Price
Quantity
Order

69227-47-0
-
-
-
- +
Online Inquiry

※ Please kindly note that our products are for research use only.

Butyltriphenylphosphonium chloride (13371-17-0)
Tributylhexadecylphosphonium Bromide (14937-45-2)
Tetraphenylphosphonium bromide (2751-90-8)
(1R,2R)-2-Amino-1-phenylpropyldiphenylphosphine (799297-44-2)
(±)-1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate (35193-63-6)
Tetraphenylphosphonium Chloride (2001-45-8)

Products

Chiral Catalysts
Ligands
Metal Catalysts
Non-Metal Catalysts
Organocatalysts
Phase Transfer Catalysts
Photocatalysts
Reaction Type

Interested in our Services & Products? Need detailed information?

Email:
Tel:
Fax:
Address: