NAVIGATION

Tel:
Fax:
Address:
Email: For product inquiries or a copy of our product catalog, please use our online system or send an email to .

(R)-Xyl-Phanephos

PRICE INQUIRY

Catalog Number

ACM325168896-1

Product Name

(R)-Xyl-Phanephos

Structure

CAS

325168-89-6

Product Overview
Usage

Synonyms

(R)-(-)-4,12-Bis[di(3,5-xylyl)phosphino]-[2.2]-paracyclophane

Molecular Weight

688.87

Molecular Formula

C48H50P2

Canonical SMILES

Cc1cc(C)cc(c1)P(c2cc(C)cc(C)c2)c3cc4CCc5ccc(CCc3cc4)cc5P(c6cc(C)cc(C)c6)c7cc(C)cc(C)c7

InChI

1S/C48H50P2/c1-31-17-32(2)22-43(21-31)49(44-23-33(3)18-34(4)24-44)47-29-39-9-13-41(47)15-11-40-10-14-42(16-12-39)48(30-40)50(45-25-35(5)19-36(6)26-45)46-27-37(7)20-38(8)28-46/h9-10,13-14,17-30H,11-12,15-16H2,1-8H3

InChI Key

LYHOBZAADXPPNW-UHFFFAOYSA-N

Melting Point

234-238 °C

Assay

0.95

Optical Activity

[α]22/D -61.0, c = 0.1 in ethanol

Application

(R)-Xyl-Phanephos serves as an efficient chiral ligand with a versatile role in various enantioselective processes. It is primarily utilized in the asymmetric hydrogenation of dehydroamino acids, methyl esters, and ketones, making it an invaluable tool in producing chiral molecules with high enantioselectivity. Furthermore, this ligand is employed in the hydroxycarbonylation and alkoxycarbonylation of alkenes, providing essential pathways for functionalization. (R)-Xyl-Phanephos also facilitates [2+2] cycloaddition reactions between oxabicyclic alkenes and terminal alkynes and enhances the gold-catalyzed enantioselective Cope rearrangement of achiral 1,5-dienes, showcasing its broad applicability in synthetic chemistry.

If you have any other questions or need other size, please get a quote.

CAS
Size
Purity
Price
Quantity
Order

325168-89-6
-
-
-
- +
Online Inquiry

※ Please kindly note that our products are for research use only.

(R)-Phanephos (364732-88-7)
(R)-An-Phanephos (364732-86-5)
(R)-1-Pyridin-2-yl-ethanol (27911-63-3)
(R)-PPhos (221012-82-4)
(R)-3-Hydroxy-butyric acid ethyl ester (24915-95-5)
Methyl (R)-3-Hydroxy-2-Methylpropionate (72657-23-9)

Products

Chiral Catalysts
Ligands
Metal Catalysts
Non-Metal Catalysts
Organocatalysts
Phase Transfer Catalysts
Photocatalysts
Reaction Type

Interested in our Services & Products? Need detailed information?

Email:
Tel:
Fax:
Address: