CAS 564483-18-7 2-Dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl

Synonyms

Dicyclohexyl(2',4',6'-Triisopropylbiphenyl-2-Yl)Phosphine

IUPAC Name

dicyclohexyl-[2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane

Molecular Weight

476.72

Molecular Formula

C33H49P

Canonical SMILES

CC(C)C1=CC(=C(C(=C1)C(C)C)C2=CC=CC=C2P(C3CCCCC3)C4CCCCC4)C(C)C;

InChI

UGOMMVLRQDMAQQ-UHFFFAOYSA-N

InChI Key

InChI=1S/C33H49P/c1-23(2)26-21-30(24(3)4)33(31(22-26)25(5)6)29-19-13-14-20-32(29)34(27-15-9-7-10-16-27)28-17-11-8-12-18-28/h13-14,19-25,27-28H,7-12,15-18H2,1-6H3

Boiling Point

569.8±50.0 °C(Predicted)

Melting Point

187-190 °C(lit.)

Purity

98%

Appearance

Solid

Complexity

545

Covalently-Bonded Unit Count

Exact Mass

476.357g/mol

Heavy Atom Count

Isomeric SMILES

CC(C)C1=CC(=C(C(=C1)C(C)C)C2=CC=CC=C2P(C3CCCCC3)C4CCCCC4)C(C)C

Monoisotopic Mass

476.357g/mol

Rotatable Bond Count

Topological Polar Surface Area

0A^2

UNII

R271FU23T8

MSDS

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COA

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Spec Sheet

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Application

Exceptional ligands for Pd-catalyzed amination and amidation of aryl sulfonates.

Ligand used for the Pd-catalyzed Suzuki-Miyaura coupling reaction and carbonyl enolate coupling.

Ligand used for the chemoselective amination of aryl chlorides.

Ligand used for the Pd-catalyzed borylation of aryl chlorides, for the formation of trifluoroborates.

Ligand used for the Pd-catalyzed amination of vinyl halides and triflates.

Ligand used for the Pd-catalyzed three-component synthesis of indoles.

Ligand used for the Pt-catalyzed regioselective hydrosilylation of functionalized terminal arylalkynes.

Ligand used for the Pd-catalyzed synthesis of carbazoles.

Ligand used for the Pd-catalyzed Suzuki-Miyaura coupling of aryl chloride and NHC-boranes.

Ligand used for the direct arylation of picoline N-oxide.

Ligand used for the Negishi coupling of 2-heterocyclic organozinc reagents.

Catalyst for a phosphine-catalyzed Heine reaction.

Ligand used for the palladium-catalyzed oxidative coupling of indoles and heteroarenes.

Ligand used for the silver-catalyzed hydrogenation of aldehydes.

Ligand used for the palladium-catalyzed cyanation of heterycyclic halides.