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Chloro(pentamethylcyclopentadienyl)bis(triphenylphosphine)ruthenium(II), 99%
PRICE INQUIRYCatalog Number
ACM92361494-2
Product Name
Chloro(pentamethylcyclopentadienyl)bis(triphenylphosphine)ruthenium(II), 99%
Structure
![{[CurrentData.Name]}](https://resource.alfachemic.com/structure/92361-49-4.gif)
CAS
92361-49-4
Synonyms
Chloro(pentamethylcyclopentadienyl)bis(triphenylphosphine)ruthenium(II)
IUPAC Name
chlororuthenium(1+);1,2,3,4,5-pentamethylcyclopenta-1,3-diene;triphenylphosphane
Molecular Weight
796.32
Molecular Formula
C46H45ClP2Ru
Canonical SMILES
C[C-]1C(=C(C(=C1C)C)C)C.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Ru+]
InChI Key
AHWRJPOOFGXEKF-UHFFFAOYSA-M
Melting Point
128ºC (D)
Purity
0.98
Appearance
orange powder
Storage
2-8°C
Exact Mass
796.17300
H-Bond Acceptor
1
H-Bond Donor
0
MDL Number
MFCD09038426
Application
Chloro(pentamethylcyclopentadienyl)bis(triphenylphosphine)ruthenium(II), 99%, serves as an effective catalyst in the cycloaddition of azides with acetylenes, uniquely facilitating the exclusive formation of 1,5-disubstituted triazoles. This contrasts with the typical 1,4-regiochemistry observed when copper catalysts are used. The ruthenium-based catalysis is particularly advantageous as it allows for the incorporation of internal acetylenes in these "click cycloadditions," broadening the scope and versatility of the reaction.
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