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Chloro[(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][2-(diphenylphosphino)ethanamine]ruthenium(II) tetrafluoroborate, min. 97%

Chloro[(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][2-(diphenylphosphino)ethanamine]ruthenium(II) tetrafluoroborate, min. 97%

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Catalog Number

ACM1150112449

Product Name

CAS

1150112-44-9

Product Overview
Reviews

Synonyms

MFCD17018818;1150112-44-9;Chloro[(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][2-(diphenylphosphino)ethanamine]ruthenium(II) tetrafluoroborate;

IUPAC Name

2-diphenylphosphanylethanamine;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;ruthenium(2+);chloride;tetrafluoroborate;

Molecular Weight

1075.274g/mol

Molecular Formula

C58H48BClF4NP3Ru;

Canonical SMILES

[B-](F)(F)(F)F.C1=CC=C(C=C1)P(CCN)C2=CC=CC=C2.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.[Cl-].[Ru+2];

InChI

InChI=1S/C44H32P2.C14H16NP.BF4.ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;15-11-12-16(13-7-3-1-4-8-13)14-9-5-2-6-10-14;2-1(3,4)5;;/h1-32H;1-10H,11-12,15H2;;1H;/q;;-1;;+2/p-1;

InChI Key

WHFVXMCYJADYIO-UHFFFAOYSA-M;

Complexity

981

Covalently-Bonded Unit Count

Exact Mass

1075.176g/mol

H-Bond Acceptor

H-Bond Donor

Heavy Atom Count

Monoisotopic Mass

1075.176g/mol

Rotatable Bond Count

Topological Polar Surface Area

26A^2

January 20, 2023

A highly efficient hydrogen transfer catalyst

For ketones and alcohols formed by carbon-carbon bonds, chloro[(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][2-(diphenylphosphino)ethanamine]ruthenium(II) tetrafluoroborate is an efficient transfer hydrogenation catalyst.

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