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Allylpalladium(II) chloride dimer

Catalog Number
ACM12012952
Product Name
Allylpalladium(II) chloride dimer
Structure
Allylpalladium(II) chloride dimer
CAS
12012-95-2
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Synonyms
Di-mu-chlorodi-pi-allyldipalladium; NSC 151255; Bis(pi-allylpalladium chloride) (VAN); MFCD00044874 (95%); Bis(mu-chloro)bis(eta3-2-propenyl)dipalladium; AK327212; 12012-95-2; Palladium, di-pi-allyldi-mu-chlorodi- (8CI); Bis((eta3-allyl)(chloro)palladium); SC10406;
IUPAC Name
chloropalladium(1+);prop-1-ene;
Molecular Weight
365.886g/mol
Molecular Formula
C6H10Cl2Pd2;
Canonical SMILES
[CH2-]C=C.[CH2-]C=C.Cl[Pd+].Cl[Pd+];
InChI
InChI=1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q2*-1;;;2*+2/p-2;
InChI Key
PENAXHPKEVTBLF-UHFFFAOYSA-L;
Storage
2-8°C
Complexity
14.4
Covalently-Bonded Unit Count
4
EC Number
234-579-8
Exact Mass
365.823g/mol
H-Bond Acceptor
2
Heavy Atom Count
10
Monoisotopic Mass
363.823g/mol
Topological Polar Surface Area
0A^2
Application
Precatalyst for the enantioselective hydrosilylation of olefins.

Precatalyst for asymmetric allylic alkylation and amination.

Used as a palladium source for cross-coupling reactions.

Can be used with Trost ligands.

Catalyst for the carbostannylation of alkynes.

Used as a precatalyst for "-arylation of aldehydes.
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