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Tris(triphenylphosphine)rhodium(I) chloride

Catalog Number
ACM14694952-1
Product Name
Tris(triphenylphosphine)rhodium(I) chloride
Structure
Tris(triphenylphosphine)rhodium(I) chloride
CAS
14694-95-2
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Synonyms
Chlorotris-(triphenylphosphino)-rhodium
IUPAC Name
rhodium;triphenylphosphane;chloride;
Molecular Weight
925.21
Molecular Formula
C54H45ClP3Rh
InChI
InChI=1S/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h3*1-15H;1H;/p-1
InChI Key
QBERHIJABFXGRZ-UHFFFAOYSA-M
Melting Point
245-250 °C
Purity
98%
Appearance
Magenta crystal
Storage
2-8°C
Complexity
202
Covalently-Bonded Unit Count
5
Defined Atom Stereocenter Count
0
EC Number
238-744-5
Exact Mass
924.14776
Formal Charge
-1
H-Bond Acceptor
1
Heavy Atom Count
59
Monoisotopic Mass
924.14776
Rotatable Bond Count
9
Topological Polar Surface Area
0 Ų
UNII
0FV534BKEV
Application
A homogeneous hydrogenation catalyst which operates under mild conditions.

Catalyst for the decarbonylation of aldehydes.

Catalyst for regio- and stereoselective allylic substitution reactions.

Alkyne hydro-phosphorylation

Heck-type reaction with α,β-unsaturated esters.

Alkyne arylation

Allylic alcohol-olefin coupling.

Terminal alkenes from ketones.

Rh-catalyzed isomerization of α-aryl propargyl alcohols to indanones.

Reductive deprotection of silyl groups.
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