NAVIGATION
- Home
- Products
- Metal Catalysts
- Platinum Catalysts
- Allylpalladium(II) chloride dimer
Allylpalladium(II) chloride dimer
Catalog Number
ACM12012952-5
Product Name
Allylpalladium(II) chloride dimer
Structure
![{[CurrentData.Name]}](https://resource.alfachemic.com/structure/12012-95-2.gif)
CAS
12012-95-2
Synonyms
Di-mu-chlorodi-pi-allyldipalladium; NSC 151255; Bis(pi-allylpalladium chloride) (VAN); MFCD00044874 (95%); Bis(mu-chloro)bis(eta3-2-propenyl)dipalladium; AK327212; 12012-95-2; Palladium, di-pi-allyldi-mu-chlorodi- (8CI); Bis((eta3-allyl)(chloro)palladium); SC10406;
IUPAC Name
chloropalladium(1+);prop-1-ene;
Molecular Weight
365.886g/mol
Molecular Formula
C6H10Cl2Pd2;
Canonical SMILES
[CH2-]C=C.[CH2-]C=C.Cl[Pd+].Cl[Pd+];
InChI
InChI=1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q2*-1;;;2*+2/p-2;
InChI Key
PENAXHPKEVTBLF-UHFFFAOYSA-L;
Storage
2-8°C
Complexity
14.4
Covalently-Bonded Unit Count
4
EC Number
234-579-8
Exact Mass
365.823g/mol
H-Bond Acceptor
2
Heavy Atom Count
10
Monoisotopic Mass
363.823g/mol
Topological Polar Surface Area
0A^2
Application
Allylpalladium(II) chloride dimer, a yellow powder with the formula [(η3-C3H5)PdCl]2, serves as a pivotal catalyst in organic synthesis, notably recognized for its role in various transition metal allyl complex reactions. It is extensively used in the Heck reaction, facilitating the formation of cyclopentadienyl allyl palladium when reacting with cyclopentadienyl anion. This compound acts as a precatalyst in numerous processes, including asymmetric and cross-coupling catalysis, contributing to the synthesis of 1,4-diallyl-1,2-dihydroisoquinolines and enabling greener Buchwald-Hartwig coupling reactions. Additionally, it plays a key role in the formation of cationic palladium catalysts and the preparation of heterocyclic carbene-palladium-η3-allyl chloride complexes, utilized in efficient Suzuki-Miyaura cross-coupling reactions. As a catalyst, it is instrumental in the silylation of organobromides, the synthesis of α-aryl carbonyl compounds via aldehyde and aryl halide coupling, and the cross-coupling of arylthiophene derivatives through C-H functionalization. Moreover, it is applied in tandem nucleophilic allylation-alkoxyallylation reactions of alkynylaldehydes, enantioselective hydrosilylation of olefins, asymmetric allylic alkylation and amination, serving as a palladium source in cross-coupling reactions, often with Trost ligands, and in the carbostannylation of alkynes, and it acts as a precursor in the α-arylation of aldehydes.
December 01, 2024
Unparalleled Catalyst for Organic Synthesis
Using Alfa Chemistry's Allylpalladium(II) chloride dimer in our lab significantly enhanced our Heck and Suzuki-Miyaura reactions. This versatile catalyst streamlined our synthesis processes, proving indispensable for efficient cross-coupling reactions.
- CAS
- Size
- Purity
- Price
- Quantity
- Order
- 12012-95-2
- -
- -
- -
-
- +
-
Online Inquiry
※ Please kindly note that our products are for research use only.
