CAS 14024-61-4 Bis(2,4-pentanedionato)palladium(II)

Synonyms

Bis(acetylacetonato)palladium(II); AKOS015964062; 2,4-PENTANEDIONE, METAL DERIVATIVE; Bis(2,4-pentanedionato)palladium(II); SC10451; MFCD00000025; Acetylacetone Palladium(II) Salt; AC-5518; 14024-61-4; Palladium(II) acetylacetonate, Vetec(TM) reagent grade, 98%;

IUPAC Name

(Z)-4-hydroxypent-3-en-2-one;palladium;

Molecular Weight

306.654g/mol

Molecular Formula

C10H16O4Pd;

Canonical SMILES

CC(=CC(=O)C)O.CC(=CC(=O)C)O.[Pd];

InChI

InChI=1S/2C5H8O2.Pd/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/b2*4-3-;;

InChI Key

BABLLCDZHABSRT-FDGPNNRMSA-N;

Storage

Store below +30°C.

Complexity

239

Covalently-Bonded Unit Count

Defined Bond Stereocenter Count

EC Number

237-859-8

Exact Mass

306.008g/mol

H-Bond Acceptor

H-Bond Donor

Heavy Atom Count

Monoisotopic Mass

306.008g/mol

Rotatable Bond Count

Topological Polar Surface Area

74.6A^2

Application

Bis(2,4-pentanedionato)palladium(II) serves as a multifunctional compound with significant applications in both medical and chemical fields. It is an active anticancer agent that has demonstrated a greater inhibitory effect on the growth of several cancer cells, including H460 cells, compared to cisplatin. Additionally, this compound acts as a versatile catalyst in a range of organic transformations, making it invaluable in chemical synthesis. It is used in the high-temperature organic solution phase protocol to produce monodisperse CuPd alloy nanoparticles and is integral in the preparation of [(NHC)Pd(acac)L] complexes, which efficiently catalyze the Heck reaction of activated aryl bromides. Furthermore, it facilitates the decarboxylative cross-coupling of arylcarboxylic acids with aryl halides. As a metal-organic complex, its sublimation properties have been studied under thermogravimetry and XRD, revealing stability in the temperature range of 100-160°C in the presence of helium, without undergoing thermal decomposition.

February 16, 2025

Highly Efficient Catalyst for Advanced Research

The Bis(2,4-pentanedionato)palladium(II) from Alfa Chemistry is outstanding. It excelled in catalyzing the Heck reaction and facilitated the synthesis of CuPd nanoparticles. Its effectiveness in diverse reactions proved invaluable in our research projects.