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(2S,3S)-(-)-Bis(diphenylphosphino)butane

Catalog Number
ACM64896282
Product Name
(2S,3S)-(-)-Bis(diphenylphosphino)butane
Structure
(2S,3S)-(-)-Bis(diphenylphosphino)butane
CAS
64896-28-2
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Synonyms
UNII-6QR78GZL9B; (2S,3S)-Butane-2,3-diylbis(diphenylphosphine); Phosphine, [(1S,2S)-1,2-dimethyl-1,2-ethanediyl]bis[diphenyl-; (-)-Chiraphos; (2S,3S)-2,3-Bis(diphenylphosphino)butane; 64896-28-2; 896B282; (2S,3S)-Chiraphos; B2704; (S,S)-Chiraphos [MI];
IUPAC Name
[(2S,3S)-3-diphenylphosphanylbutan-2-yl]-diphenylphosphane;
Molecular Weight
426.48g/mol
Molecular Formula
C28H28P2;
InChI
InChI=1S/C28H28P2/c1-23(29(25-15-7-3-8-16-25)26-17-9-4-10-18-26)24(2)30(27-19-11-5-12-20-27)28-21-13-6-14-22-28/h3-24H,1-2H3/t23-,24-/m0/s1;
InChI Key
FWXAUDSWDBGCMN-ZEQRLZLVSA-N;
Complexity
387
Covalently-Bonded Unit Count
1
Defined Atom Stereocenter Count
2
Exact Mass
426.167g/mol
Heavy Atom Count
30
Monoisotopic Mass
426.167g/mol
Rotatable Bond Count
7
Topological Polar Surface Area
0A^2
UNII
6QR78GZL9B
Application
Useful as a ligand in the Ni-catalyzed asymmetric additions to allylic ketals.
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