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(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene

Catalog Number
ACM71042541
Product Name
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene
Structure
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene
CAS
71042-54-1
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Synonyms
71042-54-1;(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE;(+)-Norphos;(2S,3S)-(+)-2,3-bis(diphenylphosphino)-bicylo[2.2.1]hept-5-ene;SCHEMBL12446363;ZINC2575216;MFCD00085364;BP-12263;(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE, MIN. 95% (S,S)-NORPHOS;
IUPAC Name
[(1R,2S,3S,4S)-3-diphenylphosphanyl-2-bicyclo[2.2.1]hept-5-enyl]-diphenylphosphane;
Molecular Weight
462.513g/mol
Molecular Formula
C31H28P2;
InChI
InChI=1S/C31H28P2/c1-5-13-26(14-6-1)32(27-15-7-2-8-16-27)30-24-21-22-25(23-24)31(30)33(28-17-9-3-10-18-28)29-19-11-4-12-20-29/h1-22,24-25,30-31H,23H2/t24-,25+,30-,31-/m0/s1;
InChI Key
CDJHPMXMJUCLPA-QHNMYUOLSA-N;
Complexity
543
Covalently-Bonded Unit Count
1
Defined Atom Stereocenter Count
4
Exact Mass
462.167g/mol
Heavy Atom Count
33
Monoisotopic Mass
462.167g/mol
Rotatable Bond Count
6
Topological Polar Surface Area
0A^2
Application
Ligand used in the enantioselective rhodium catalyzed hydrogenation of α-dehydroaminoesters and enamides.

Ligand used in the enantioselective rhodium catalyzed hydroboration of cyclopropenes.

Ligand used in the asymmetric rhodium catalyzed cleavage of racemic 1,3-oxazolidines.
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