CAS 146960-90-9 1,1'-Bis(dicyclohexylphosphino)ferrocene

Synonyms

1,1′-Bis(dicyclohexylphosphino)ferrocene; 1,1-Bis(Dicyclohexylphosphino)Ferrocene; 1,1-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE;

IUPAC Name

dicyclohexyl(cyclopentyl)phosphane;iron

Molecular Weight

578.57

Molecular Formula

C₃₄H₅₂FeP₂

Canonical SMILES

C1CCC(CC1)P(C2CCCCC2)[C]3[CH][CH][CH][CH]3.C1CCC(CC1)P(C2CCCCC2)[C]3[CH][CH][CH][CH]3.[Fe]

InChI Key

LVWMUECONASIMT-UHFFFAOYSA-N

Melting Point

134-136ºC

Purity

98%

Appearance

Orange-red powder

Exact Mass

578.28900

MSDS

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COA

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Spec Sheet

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Application

Ligand for palladium-catalyzed synthesis of oxindoles by amide ɑ-arylation.

Ligand for palladium-catalyzed alkoxycarbonylation of aryl chlorides.

Ligand for ruthenium-catalyzed alcohol-allene C-C coupling reaction via hydrohydroxyalkylation of 1,1-disubstituted allenes employing alcohols.

Ligand for nickel-catalyzed cross-coupling reaction of arylboronic acids with aryl carbonates.

Ligand for palladium-catalyzed regiodivergent hydroesterification of aryl olefins with phenyl formate to form linear structured phenyl arylpropanoates.

Ligand for palladium-catalyzed direct borylation of benzyl alcohol and its analogues in the absence of bases.