CAS 12131-44-1 Palladium(II)(π-cinnamyl) Chloride Dimer

Synonyms

12131-44-1;Palladium(|Eth-cinnamyl) chloride dimer;AK136149;PALLADIUM(PI-CINNAMYL) CHLORIDE DIMER;Di- -chlorobis[(1,2,3- )-1-phenyl-2-propen-1-yl]dipalladium;Di-|I-chlorobis[(1,2,3-|C)-1-phenyl-2-propen-1-yl]dipalladium;Di-|I-chlorobis[(1,2,3-|C)-1-phenyl-2-propenyl]dipalladium(II);Di-mu-chlorobis[(1,2,3-eta)-1-phenyl-2-propen-1-yl]dipalladium;

IUPAC Name

palladium(2+);prop-2-enylbenzene;dichloride;

Molecular Weight

518.082g/mol

Molecular Formula

C18H18Cl2Pd2;

InChI

InChI=1S/2C9H9.2ClH.2Pd/c2*1-2-6-9-7-4-3-5-8-9;;;;/h2*2-8H,1H2;2*1H;;/q2*-1;;;2*+2/p-2;

InChI Key

PHDNDSSMEIRHSI-UHFFFAOYSA-L;

Complexity

Covalently-Bonded Unit Count

Exact Mass

517.886g/mol

H-Bond Acceptor

Heavy Atom Count

Monoisotopic Mass

515.886g/mol

Rotatable Bond Count

Topological Polar Surface Area

0A^2

MSDS

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COA

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Spec Sheet

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Application

Precursor for the preparation of a palladium catalyst used in the carbonylative arylation of ketones, yielding vinylbenzoate compounds.

Precursor for the preparation of a palladium catalyst used in the Buchwald-Hartwig amination of (hetero)aryl chlorides.

Precursor for the preparation of a palladium catalyst used in the arylative dearomatization of phenols.

Versatile palladium precursor for the preparation of palladium catalysts used in the cross-coupling of aryl chlorides and amines , conversion of aryl triflates to aryl fluorides , and the α-arylation of aldehydes .