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A monodentate phosphine ligand refers to a ligand having only one coordinating atom, and this coordinating atom is a P atom. Compared with other ligands, monophosphine ligands are easy to synthesize, flexible in structure, and excellent in catalytic performance. Therefore, the application value of monodentate phosphine ligands is very large. In addition, monodentate phosphine ligands are abundant in variety and have a wide range of applications, so they have a pivotal position in many fields.
Monodentate phosphine ligands are applied in organic synthesis, analytical chemistry, and pharmaceutical industries due to their good structural properties, diversity, and high economics.
Due to the wide variety of monodentate phosphine ligands, they can be classified into different types according to different classification methods. Monodentate phosphine ligands can be classified into achiral monodentate phosphine ligands, planar chiral monodentate phosphine ligands, and axial chiral monodentate phosphine ligands depending on the presence or absence of chirality. The monodentate phosphine ligands can be mainly classified into simple phosphine ligands, phosphoramidite ligands, phosphonite ligands, phosphite ligands and other types of monophosphine ligands according to the atomic species bonded to the phosphorus atom.
Figure 1. Simple phosphine ligand
Figure 2. Phosphoramidite ligand
Figure 3. Phosphoramidite ligand
Figure 4. Phosphite ligand
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