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Tetraphenylphosphonium bromide

Catalog Number
ACM2751908-1
Product Name
Tetraphenylphosphonium bromide
Structure
Tetraphenylphosphonium bromide
CAS
2751-90-8
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Synonyms
Tetraphenyl-phosphoniubromide
IUPAC Name
tetraphenylphosphanium;bromide;
Molecular Weight
419.29
Molecular Formula
C24H20BrP
InChI
InChI=1S/C24H20P.BrH/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;/h1-20H;1H/q+1;/p-1
InChI Key
BRKFQVAOMSWFDU-UHFFFAOYSA-M
Melting Point
295-300 °C
Purity
99%
Solubility
Soluble in water
Appearance
White to off-white crystalline powder
Storage
Inert atmosphere, Room Temperature
Complexity
301
Covalently-Bonded Unit Count
2
EC Number
220-393-4
Exact Mass
418.0486
H-Bond Acceptor
1
Heavy Atom Count
26
Monoisotopic Mass
418.0486
NSC Number
115672
Physical State
Off-white solid
Rotatable Bond Count
4
Topological Polar Surface Area
0 Ų
Application
Tetraphenylphosphonium bromide is also known as TPP, TPP-Br, TPPB and TPPBr.Tetraphenylphosphonium bromide is a quaternary phosphonium salt mainly used in pharmaceuticals, as accelarator for fluoroelastomers , adhesion promotor for fluoroelastomers and curative of polyacrylate polymers which extends the shelf life of the compound and decreases the mould fouling. This material is highly soluble in water and slightly soluble in alcohols.

Tetraphenylphosphonium bromide is a supporting electrolyte for the electroreduction of buckminsterfullerene.

It is used to extract heavy metals from aqueous solution as ion-association complexes.

Recently, tetraphenylphosphonium bromide (TPPB) has been used to remove technetium from some radioactive waste streams.
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