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Tetrakis[(R)-(+)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II) Rh2(R-DOSP)4

Catalog Number
ACM178879602
Product Name
Tetrakis[(R)-(+)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II) Rh2(R-DOSP)4
Structure
Tetrakis[(R)-(+)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II) Rh2(R-DOSP)4
CAS
178879-60-2
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Synonyms
AKOS015909399; 178879-60-2; Tetrakis[(R)-(+)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II), AldrichCPR; MFCD04974245; TETRAKIS[(R)-(+)-N-(4-DODECYLPHENYLSULFONYL)PROLINATO]DIRHODIUM(II); TETRAKIS[(R)-(+)-N-(P-DODECYLPHENYLSULFONYL)PROLINATO]DIRHODIUM(II);
IUPAC Name
(2R)-1-(4-dodecylphenyl)sulfonylpyrrolidine-2-carboxylic acid;rhodium;
Molecular Weight
1900.259g/mol
Molecular Formula
C92H148N4O16Rh2S4;
InChI
InChI=1S/4C23H37NO4S.2Rh/c4*1-2-3-4-5-6-7-8-9-10-11-13-20-15-17-21(18-16-20)29(27,28)24-19-12-14-22(24)23(25)26;;/h4*15-18,22H,2-14,19H2,1H3,(H,25,26);;/t4*22-;;/m1111../s1;
InChI Key
IGTBJBHOQXYDMM-MSZWWGBCSA-N;
Complexity
1240
Covalently-Bonded Unit Count
6
Defined Atom Stereocenter Count
4
Exact Mass
1898.788g/mol
H-Bond Acceptor
20
H-Bond Donor
4
Heavy Atom Count
118
Monoisotopic Mass
1898.788g/mol
Rotatable Bond Count
56
Topological Polar Surface Area
332A^2
Application
Catalyst used for tandem asymmetric cyclopropanation/Cope rearrangement.

Catalyst used for an asymmetric [4 + 3] cycloaddition.
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