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(S,S)-1,2-Bis[(2-methoxyphenyl)phenylphosphino]ethane

Catalog Number
ACM97858623
Product Name
(S,S)-1,2-Bis[(2-methoxyphenyl)phenylphosphino]ethane
Structure
(S,S)-1,2-Bis[(2-methoxyphenyl)phenylphosphino]ethane
CAS
97858-62-3
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Synonyms
Ethylenebis[(S)-(o-anisyl)(phenyl)phosphine]; MFCD05863547; (S,S)-DIPAMP, >=95%; AB1011200; (1S,2S)-(+)-Bis[(2-methoxyphenyl)phenylphosphino]ethane; UNII-HS6F5EW3U6; OR310819; ST24036672;
IUPAC Name
(S)-(2-methoxyphenyl)-[2-[(2-methoxyphenyl)-phenylphosphanyl]ethyl]-phenylphosphane;
Molecular Weight
458.478g/mol
Molecular Formula
C28H28O2P2;
Canonical SMILES
COC1=CC=CC=C1P(CCP(C2=CC=CC=C2)C3=CC=CC=C3OC)C4=CC=CC=C4;
InChI
InChI=1S/C28H28O2P2/c1-29-25-17-9-11-19-27(25)31(23-13-5-3-6-14-23)21-22-32(24-15-7-4-8-16-24)28-20-12-10-18-26(28)30-2/h3-20H,21-22H2,1-2H3/t31-,32-/m0/s1;
InChI Key
QKZWXPLBVCKXNQ-ACHIHNKUSA-N;
Complexity
472
Covalently-Bonded Unit Count
1
Defined Atom Stereocenter Count
2
Exact Mass
458.156g/mol
H-Bond Acceptor
2
Heavy Atom Count
32
Monoisotopic Mass
458.156g/mol
Rotatable Bond Count
9
Topological Polar Surface Area
18.5A^2
UNII
HS6F5EW3U6
Application
Rhodium DIPAMP catalysts have shown high activity and enantioselectivity in the asymmetric hydrogenation of enamides, enol acetates and olefins.
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