Molecular Weight
648.98
Molecular Formula
C20H21Cl3O2PReS
Purity
97%
Appearance
Powder
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- Oxotrichloro[(dimethylsulfide)triphenylphosphine oxide]rhenium(V)
Oxotrichloro[(dimethylsulfide)triphenylphosphine oxide]rhenium(V)
Catalog Number
ACM108695905
Product Name
Oxotrichloro[(dimethylsulfide)triphenylphosphine oxide]rhenium(V)
CAS
108695-90-5
Application
Oxotrichloro[(dimethylsulfide)triphenylphosphine oxide]rhenium(V) serves as a versatile catalyst and reagent in a variety of chemical transformations. It is employed in the enantioselective reduction of ketones and imines, contributing to the synthesis of chiral compounds. Additionally, it facilitates the Meyer-Schuster rearrangement of propargylic alcohols to yield α, β-unsaturated carbonyl compounds. The compound also plays a crucial role in the synthesis of 2-deoxy-α glycosides, and it is effective in sulfurizing phosphorus(III) compounds with thiiranes. Beyond these applications, it acts as a reactant in the synthesis of mono and dinuclear compounds and as a reagent in producing rhenium-cyclized somatostatin derivative series, highlighting its multifaceted utility in advanced chemical synthesis.
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