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Gallium(III) oxide

Catalog Number
ACM12024214
Product Name
Gallium(III) oxide
Structure
Gallium(III) oxide
CAS
12024-21-4
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Synonyms
Digallium trioxide
IUPAC Name
oxo(oxogallanyloxy)gallane
Molecular Weight
187.44
Molecular Formula
Ga2O3
InChI Key
QZQVBEXLDFYHSR-UHFFFAOYSA-N
Melting Point
1,900° C (3,452° F)
Purity
99%, 99.9%, 99.99%, 99.999%
Density
5.88 g/cm³
Appearance
White Powder
Exact Mass
187.85200
H-Bond Acceptor
3
H-Bond Donor
0
MDL Number
MFCD00011020
Stability
Stable. Incompatible with magnesium.
Application
Gallium sesquioxide is reduced to gallium suboxide, Ga2O [12024-20-3] by common reducing agents. Also, heating the sesquioxide with gallium metal yields gallium suboxide. Heating with magnesium reduces the oxide to elemental form in a violent reaction:

Ga2O3 + 3Mg →2Ga + 3MgO

Heating with mineral acids yields corresponding gallium salts. When heated with a mixture of hydrogen and arsenic vapors at 600°C, gallium arsenide, GaAs is produced. When heated with alkali metal oxide at 1,000°C, alkali metal gallates, such as K2Ga2O6 are formed.
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