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Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II), min. 98%

Catalog Number
ACM127593286
Product Name
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II), min. 98%
Structure
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II), min. 98%
CAS
127593-28-6
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Synonyms
ST24050377; 5353AA; DICHLORO[2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II); 115826-95-4; [(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM (II) CHLORIDE; FT-0696081; MFCD00075254; C44H32Cl2P2Pd; EBD2199625; PALLADIUM, [1,1'-(1R)-[1,1'-BINAPHTHALENE]-2,2'-DIYLBIS[1,1-DIPHENYLPHOSPHINE-KAPPAP]]DICHLORO-, (SP-4-2)-;
IUPAC Name
dichloropalladium;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;
Molecular Weight
800.008g/mol
Molecular Formula
C44H32Cl2P2Pd;
InChI
InChI=1S/C44H32P2.2ClH.Pd/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;;;/h1-32H;2*1H;/q;;;+2/p-2;
InChI Key
VDHAUMFISVWIRX-UHFFFAOYSA-L;
Complexity
800
Covalently-Bonded Unit Count
2
Exact Mass
798.039g/mol
Heavy Atom Count
49
Monoisotopic Mass
798.039g/mol
Rotatable Bond Count
7
Topological Polar Surface Area
0A^2
Application
Catalyst precursor, with AgBF4 , for the enantioselective addition of silyl ethers, to imines to produce β-amino ketones, and to aldehydes to produce 3-hydroxy-1-propanone aldol addition products.

Catalyst precursor, with AgSbF6, for the asymmetric carbonyl-ene reaction.

Catalyst precursor for hetero Diels-Alder reaction of simple dienes with aldehydes and aryl glyoxals.
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