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Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(II) dichloride, min. 97%

Catalog Number
ACM219770997
Product Name
Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(II) dichloride, min. 97%
Structure
Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(II) dichloride, min. 97%
CAS
219770-99-7
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Synonyms
Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(IV) dichloride; SCHEMBL995991; BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM(II) DICHLORIDE; Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(II)dichloride; SC10225; 437767-65-2;
IUPAC Name
dichloro(phenylsulfanylmethylidene)ruthenium;tricyclohexylphosphane;
Molecular Weight
855.027g/mol
Molecular Formula
C43H72Cl2P2RuS;
InChI
InChI=1S/2C18H33P.C7H6S.2ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-8-7-5-3-2-4-6-7;;;/h2*16-18H,1-15H2;1-6H;2*1H;/q;;;;;+2/p-2;
InChI Key
UDWHYAPPVOEOMP-UHFFFAOYSA-L;
Complexity
341
Covalently-Bonded Unit Count
3
Exact Mass
854.325g/mol
H-Bond Acceptor
1
Heavy Atom Count
49
Monoisotopic Mass
854.325g/mol
Rotatable Bond Count
8
Topological Polar Surface Area
25.3A^2
Application
Metathesis catalyst, stable in air and can be used in aqueous media.

Catalyst of choice for the ring-opening metathesis polymerization of cycloolefins.

Catalyst concentration 2-3 times lower than comparable phenyl and vinyl substituted ruthenium carbenes.

Excellent initiator for solvent-free polymerization and control of initiation rates and gelation times.

Highly selective catalyst for the ring opening/cross-metathesis of norbornene derivatives.
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