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Bis(tri-tert-butylphosphine)platinum(0)

Catalog Number
ACM60648706
Product Name
Bis(tri-tert-butylphosphine)platinum(0)
Structure
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CAS
60648-70-6
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Synonyms
Platinum;tritert-butylphosphane
IUPAC Name
platinum;tritert-butylphosphane;
Molecular Weight
599.7
Molecular Formula
C24H54P2Pt
Canonical SMILES
CC(C)(C)P(C(C)(C)C)C(C)(C)C.CC(C)(C)P(C(C)(C)C)C(C)(C)C.[Pt]
InChI
InChI=1S/2C12H27P.Pt/c2*1-10(2,3)13(11(4,5)6)12(7,8)9;/h2*1-9H3;
InChI Key
RJQWVEJVXWLMRE-UHFFFAOYSA-N
Melting Point
260-269 °C
Purity
98%
Appearance
Powder
Storage
2-8°C
Complexity
128
Covalently-Bonded Unit Count
3
Defined Atom Stereocenter Count
0
Exact Mass
599.33487
Heavy Atom Count
27
Monoisotopic Mass
599.33487
Rotatable Bond Count
6
Topological Polar Surface Area
0 Ų
Application
Bis(tri-tert-butylphosphine)platinum(0) serves as a versatile agent in several advanced chemical syntheses and catalytic processes. It is utilized as a reactant in the creation of unique trimetallic ReBiPt and rhodium-germanium carbonyl complexes. Additionally, it functions as a catalyst in the synthesis of amidobipyridyl inhibitors targeting protein kinase D and the production of 5-fluoroalkylated pyrimidine nucleosides through Negishi cross-coupling. Furthermore, it facilitates the transfer of phenyl and methyl groups from tin to iridium and acts as an activator for metal hydride complexes, demonstrating its broad applicability in various chemical transformations.
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