CAS 36620-11-8 Bis[η-(2,5-norbornadiene)]rhodium(I) Tetrafluoroborate

Synonyms

36620-11-8; Bis(norbornadiene)rhodium(I) tetrafluoroborate; [rh(nbd)2]bf4; SC-49716; Bis(bicyclo[2.2.1]hepta-2,5-diene)rhodium tetrafluoroborate; ANW-41403; MFCD00671775; Bis(norbornadiene)(tetrafluoroborato)rhodium; bis(norbomadiene)rhodium (I) tetrafluoroborate; Bis(norbornadiene)rhodium (I) tetrafluoroborate;

IUPAC Name

bicyclo[2.2.1]hepta-2,5-diene;rhodium;tetrafluoroborate;

Molecular Weight

373.991g/mol

Molecular Formula

C14H16BF4Rh-;

Canonical SMILES

[B-](F)(F)(F)F.C1C2C=CC1C=C2.C1C2C=CC1C=C2.[Rh];

InChI

InChI=1S/2C7H8.BF4.Rh/c2*1-2-7-4-3-6(1)5-7;2-1(3,4)5;/h2*1-4,6-7H,5H2;;/q;;-1;;

InChI Key

ZWPWNBFOFVFMPP-UHFFFAOYSA-N;

Storage

Refrigerator

Complexity

122

Covalently-Bonded Unit Count

Exact Mass

374.034g/mol

Formal Charge

-1

H-Bond Acceptor

Heavy Atom Count

Monoisotopic Mass

374.034g/mol

Topological Polar Surface Area

0A^2

MSDS

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COA

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Spec Sheet

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Application

Bis{P,P'-1,5-diphenyl-3,7-bis[(4-hydrogenphosphonate)phenyl]-1,5,3,7-diazadiphosphocine} nickel(II) bromide (hydrogen bromide adduct) can be used as Synthetic nickel catalyst used for photocatalytic reduction of aqueous protons to hydrogen and catalyst containing phosphonate anchor groups for immobilation on metal oxide semiconductor surfaces, enabling light-driven hydrogen evolution.