CAS 72914-19-3 4,4'-Di-tert-butyl-2,2'-bipyridine

Synonyms

BBBPY; 4-tert-butyl-2-(4-tert-butylpyridin-2-yl)pyridine

IUPAC Name

4-tert-butyl-2-(4-tert-butylpyridin-2-yl)pyridine

Molecular Weight

268.40

Molecular Formula

C18H24N2

Canonical SMILES

CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C

InChI

TXNLQUKVUJITMX-UHFFFAOYSA-N

InChI Key

InChI=1S/C18H24N2/c1-17(2,3)13-7-9-19-15(11-13)16-12-14(8-10-20-16)18(4,5)6/h7-12H,1-6H3

Boiling Point

395.4±42.0 °C(Predicted)

Melting Point

159-161 °C-lit.

Purity

98%

Appearance

White solid

Complexity

278

Covalently-Bonded Unit Count

Exact Mass

268.193948774

H-Bond Acceptor

Heavy Atom Count

Monoisotopic Mass

268.193948774

Rotatable Bond Count

Topological Polar Surface Area

25.8 Å²

MSDS

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COA

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Spec Sheet

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Application

Ligand for the iridium-catalyzed borylation of arenes

Ligand for the iridium-catalyzed synthesis of arylboronic acids and aryl trifluoroborates

Ligand for the nickel-catalyzed hydroxycarboxylation of 1,2-dienes by reaction carbon dioxide and oxygen

Ligand for the iridium-catalyzed meta borylation followed by halogenation of 1,3-disubstituted arenes

Ligand for the iridium-catalyzed silyl-directed ortho-borylation of arenes

Ligand for the iridium-catalyzed silane borylation followed by aryl borylation

Ligand for the iridium-catalyzed microwave-accelerated borylation of aromatic C-H bonds

Ligand for the iridium-catalyzed silyl-directed borylation of indoles

Ligand for the nickel-catalyzed synthesis of functionalized dialkyl ketones from carboxylic acids and alkyl halides

Ligand for the iron-catalyzed arylation of heterocycles