CAS 564483-19-8 2-Di-tert-butylphosphino-2',4',6'-triisopropylbiphenyl

Synonyms

DTXSID70469549; t-Bu XPhos; FT-0689983; TC-121258; 2-Di-tert-butylphosphino-2 inverted exclamation marka,4 inverted exclamation marka,6 inverted exclamation marka-triisopropylbiphenyl; tBuXPhos; ditert-butyl-[2-(2,4,6-triisopropylphenyl)phenyl]phosphane; ZINC56961724; 2-Di-tert-butylphosphino-2',4',6'-triisopropylbiphenyl; 2-(di-tert-butylphosphino)-2', 4',6'-triisopropylbiphenyl;

IUPAC Name

ditert-butyl-[2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane;

Molecular Weight

424.653g/mol

Molecular Formula

C29H45P;

Canonical SMILES

CC(C)C1=CC(=C(C(=C1)C(C)C)C2=CC=CC=C2P(C(C)(C)C)C(C)(C)C)C(C)C;

InChI

InChI=1S/C29H45P/c1-19(2)22-17-24(20(3)4)27(25(18-22)21(5)6)23-15-13-14-16-26(23)30(28(7,8)9)29(10,11)12/h13-21H,1-12H3;

InChI Key

SACNIGZYDTUHKB-UHFFFAOYSA-N;

Complexity

486

Covalently-Bonded Unit Count

Exact Mass

424.326g/mol

Heavy Atom Count

Monoisotopic Mass

424.326g/mol

Rotatable Bond Count

Topological Polar Surface Area

0A^2

MSDS

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COA

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Spec Sheet

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Application

Effective ligand for the Pd-catalyzed arylation of pyrazoles, indazoles and amino heterocycles.

Ligand used in the Pd-catalyzed synthesis of phenols from aryl halides and KOH.

Ligand used in the Pd-catalyzed of benzoic acids from aryl halides and CO2.

Ligand used in the Pd-catalyzed trifluoromethylation of vinyl sulfonates.

Ligand used in the Pd-catalyzed arylation of nitroacetates.

Ligand used in the Pd-catalyzed Suzuki−Miyaura cross-coupling of allylboronates and aryl halides.

Ligand used in the Pd-catalyzed cyanation of (hetero)arylchlorides and bromides.

Ligand used in the Pd-catalyzed C-N cross coupling of sulfinamides and aryl halides.

Ligand used in the Pd-catalyzed arylation of cyanamides.