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2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl

Catalog Number
ACM98327878
Product Name
2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
Structure
2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
CAS
98327-87-8
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Synonyms
F0001-2326; DB-009478; AC1LCPMX; (S)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL; AN-10356; SC-19338; (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene, puriss.; PubChem8136; TL8005203; (S)-(-)-2,2 inverted exclamation mark -Bis(diphenylphosphino)-1,1 inverted exclamation mark -binaphthalene;
IUPAC Name
[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;
Molecular Weight
622.688g/mol
Molecular Formula
C44H32P2;
InChI
InChI=1S/C44H32P2/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38/h1-32H;
InChI Key
MUALRAIOVNYAIW-UHFFFAOYSA-N;
Complexity
797
Covalently-Bonded Unit Count
1
EC Number
616-304-7
Exact Mass
622.198g/mol
Heavy Atom Count
46
Monoisotopic Mass
622.198g/mol
Rotatable Bond Count
7
Topological Polar Surface Area
0A^2
UNII
4F1X2F8NA3
Application
Phosphine Ligand Kit component.





Useful ligand for palladium-catalyzed carbon-nitrogen bond formation.

Useful ligand for rhodium-catalyzed C-C bond formation.

Useful ligand for palladium-catalyzed intramolecular acylation of aryl bromides via C-H activation.

Used in the preparation of Buchwald third generation precatalyst.

Used in methoxy directed Rhodium migration.

Used in Nickel catalyzed C-N cross-coupling reactions.
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