CAS 219143-92-7 (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]chromium(III) chloride

Synonyms

SCHEMBL2189792;219143-92-7;(S,S)-N,N -Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) chloride;

IUPAC Name

chromium;2,4-ditert-butyl-6-[[(1S,2S)-2-[(3,5-ditert-butyl-2-hydroxyphenyl)methylideneamino]cyclohexyl]iminomethyl]phenol;chloride;

Molecular Weight

634.286g/mol

Molecular Formula

C36H54ClCrN2O2-;

InChI

InChI=1S/C36H54N2O2.ClH.Cr/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;/h17-22,29-30,39-40H,13-16H2,1-12H3;1H;/p-1/t29-,30-;;/m0../s1;

InChI Key

URIXSIRVKMNVQX-ARDORAJISA-M;

Complexity

800

Covalently-Bonded Unit Count

Defined Atom Stereocenter Count

EC Number

606-861-4

Exact Mass

633.328g/mol

Formal Charge

-1

H-Bond Acceptor

H-Bond Donor

Heavy Atom Count

Monoisotopic Mass

633.328g/mol

Rotatable Bond Count

Topological Polar Surface Area

65.2A^2

MSDS

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COA

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Spec Sheet

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Application

Catalyst for the asymmetric ring-opening of meso-epoxides and for the kinetic resolution of terminal epoxides.

Precatalyst for asymmetric Diels-Alder and hetero Diels-Alder reactions.

Catalyst for copolymerization of CO2 and epoxides.

Catalyst for enantioselective alkylation of tributyltin enolates.

Enantioselective addition of Me2Zn to aldehydes.

Enantioselective intramolecular addition of tertiary enamides to ketones.

Asymmetric iodocyclization.

Catalytic intermolecular linear allylic C-H animation.

Cocatalyst for enantioselective ring opening of epoxides with fluoride.