Application
Zinc di[bis(trifluoromethylsulfonyl)imide] serves as a versatile catalyst, primarily aimed at facilitating various chemical reactions with high efficiency and specificity. It is utilized in the enantioselective Friedel-Crafts alkylation of pyrroles with β-CF3 acrylates, enabling the creation of chiral compounds. Additionally, it is pivotal in stereoselective Diels-Alder reactions, enhancing reaction outcomes through precise control over product stereochemistry. The compound also excels in promoting the tandem cyclopropane ring-opening and Conia-ene cyclization processes, as well as catalyzing aromatic nitration efficiently. Its utility extends to Friedel-Crafts acylations conducted in ionic liquids or without solvents, offering an excellent catalytic performance in such conditions. Furthermore, it actively facilitates cyclopropane ring-opening reactions and plays a significant role in asymmetric Friedel-Crafts reactions involving pyrroles and acrylates, underscoring its broad applicability as a catalyst in organic synthesis.