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Tris(triphenylsiloxy)vanadium oxide
Catalog Number
ACM18822509
Product Name
Tris(triphenylsiloxy)vanadium oxide
CAS
18822-50-9
Synonyms
Hydroxy(triphenyl)silane;oxovanadium
IUPAC Name
hydroxy(triphenyl)silane; oxovanadium
Molecular Weight
896.1
Molecular Formula
C54H48O4Si3V
Canonical SMILES
C1=CC=C(C=C1)[Si](C2=CC=CC=C2)(C3=CC=CC=C3)O.C1=CC=C(C=C1)[Si](C2=CC=CC=C2)(C3=CC=CC=C3)O.C1=CC=C(C=C1)[Si](C2=CC=CC=C2)(C3=CC=CC=C3)O.O=[V]
InChI
InChI=1S/3C18H16OSi.O.V/c3*19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h3*1-15,19H;
InChI Key
NTKZUWDMQWHMBP-UHFFFAOYSA-N
Boiling Point
388.6ºC at 760 mmHg
Melting Point
224-226 °C
Flash Point
188.8ºC
Purity
95%+
Complexity
891
Covalently-Bonded Unit Count
4
Defined Atom Stereocenter Count
0
Exact Mass
895.229997
H-Bond Acceptor
4
H-Bond Donor
3
Heavy Atom Count
62
Monoisotopic Mass
895.229997
NSC Number
349960
Rotatable Bond Count
9
Topological Polar Surface Area
77.8 Ų
Application
Tris(triphenylsiloxy)vanadium oxide serves as a versatile catalyst designed to enhance various chemical reactions, including its role in dual catalyst systems for the Meyer-Schuster rearrangement, facilitating the esterification process, and promoting the addition of propargyl alcohols to imines or aldehydes. Additionally, it is instrumental in the photochemical polymerization of methyl methacrylate, showcasing its broad applicability in synthetic chemistry.
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