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Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III)
Catalog Number
ACM14324993-2
Product Name
Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III)
Structure
![{[CurrentData.Name]}](https://resource.alfachemic.com/structure/14324-99-3.gif)
CAS
14324-99-3
Synonyms
Bis-(2,2,6,6-tetramethyl-3,5-heptandionato)manganese(III)
IUPAC Name
Manganese(3+);(Z)-2,2,6,6-tetramethyl-5-oxohept-3-en-3-olate
Molecular Weight
604.7
Molecular Formula
C33H60MnO6;
Canonical SMILES
CC(C)(C)C(=CC(=O)C(C)(C)C)[O-].CC(C)(C)C(=CC(=O)C(C)(C)C)[O-].CC(C)(C)C(=CC(=O)C(C)(C)C)[O-].[Mn+3]
InChI
InChI=1S/3C11H20O2.Mn/c3*1-10(2,3)8(12)7-9(13)11(4,5)6;/h3*7,12H,1-6H3;/q;+3/p-3/b3*8-7-;
InChI Key
ORZPLLPBZHORSD-LWTKGLMZSA-K
Boiling Point
255 °C
Melting Point
165 °C
Purity
95%+
Appearance
Black crystal
Storage
Under inert gas (nitrogen or Argon) at 2-8 °C
Complexity
199
Covalently-Bonded Unit Count
4
Defined Bond Stereocenter Count
3
Exact Mass
604.353558
H-Bond Acceptor
6
H-Bond Donor
3
Heavy Atom Count
40
Monoisotopic Mass
604.353558
Rotatable Bond Count
9
Topological Polar Surface Area
120 Ų
Application
Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III) serves a multifaceted role in advanced chemical processes. It acts as an effective catalyst for intramolecular Diels-Alder reactions and facilitates the borylation process. The compound also plays a critical role in the enantioselective synthesis, offering precision in producing enantiomerically pure substances. Its capabilities extend to hydrohydrazination and hydroazidation reactions, enhancing the efficiency and selectivity of these transformations. Additionally, it serves as a single electron donor in studies of excess electron transfer in DNA, contributing to the understanding of electron dynamics in biological systems. Finally, it is instrumental in the oxidative carbonylation of phenol, showcasing its versatility and utility in complex chemical syntheses.
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