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- Tris(2,4-pentanedionato)ruthenium(III)
Tris(2,4-pentanedionato)ruthenium(III)
Catalog Number
ACM14284936-7
Product Name
Tris(2,4-pentanedionato)ruthenium(III)
Structure
![{[CurrentData.Name]}](https://resource.alfachemic.com/structure/14284-93-6.gif)
CAS
14284-93-6
Synonyms
14284-93-6; O526; 2,4-PENTANEDIONE RUTHENIUM(III); Ruthenium (III) acetylacetonate; Ruthenium acetylacetonate; RUTHENIUMACETYLACETONATE; Acetylacetone Ruthenium(III) Salt; TRIS(PENTANE-2,4-DIONATO)RUTHENIUM(III); Ru(acac)3; PENTANE-2,4-DIONE, RUTHENIUM;
IUPAC Name
(Z)-4-hydroxypent-3-en-2-one;ruthenium;
Molecular Weight
401.421g/mol
Molecular Formula
C15H24O6Ru;
Canonical SMILES
CC(=CC(=O)C)O.CC(=CC(=O)C)O.CC(=CC(=O)C)O.[Ru];
InChI
InChI=1S/3C5H8O2.Ru/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/b3*4-3-;;
InChI Key
IYWJIYWFPADQAN-LNTINUHCSA-N;
Storage
Store below +30°C.
Complexity
380
Covalently-Bonded Unit Count
4
Defined Bond Stereocenter Count
3
EC Number
238-193-0
Exact Mass
402.062g/mol
H-Bond Acceptor
6
H-Bond Donor
3
Heavy Atom Count
22
Monoisotopic Mass
402.062g/mol
Rotatable Bond Count
3
Topological Polar Surface Area
112A^2
Application
Tris(2,4-pentanedionato)ruthenium(III) serves as a versatile compound primarily characterized by its dark-red crystalline form. It functions as a precursor for synthesizing various other ruthenium compounds. This product is notably utilized as a recyclable catalyst in diverse organic transformations, including the acetylation of phenols, alcohols, and amines under neat conditions. Moreover, it acts as a homogeneous catalyst in specific reactions such as the hydrolysis of sodium borohydride and regiospecific tritiation of aromatic carboxylic acids. Additionally, it is employed in the enantioselective hydrogenation of acids, like aryl acrylic acid and aryl propenic acid, underscoring its critical role in facilitating efficient and selective chemical processes.
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