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Tris(2,4-pentanedionato)iridium(III)

Catalog Number
ACM15635877-3
Product Name
Tris(2,4-pentanedionato)iridium(III)
CAS
15635-87-7
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Synonyms
Iridium(III) acetylacetonate, 97%; Iridium(iii)acetylacetonate; 15635-87-7; Y1427; Ir(acac)3; TRIS(ACETYLACETONATO)IRIDIUM(III); Tris(2,4-pentanedionato)iridium(III); C15H21IrO6;
IUPAC Name
(Z)-4-hydroxypent-3-en-2-one;iridium;
Molecular Weight
492.568g/mol
Molecular Formula
C15H24IrO6;
Canonical SMILES
CC(=CC(=O)C)O.CC(=CC(=O)C)O.CC(=CC(=O)C)O.[Ir];
InChI
InChI=1S/3C5H8O2.Ir/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/b3*4-3-;;
InChI Key
AZFHXIBNMPIGOD-LNTINUHCSA-N;
Complexity
380
Covalently-Bonded Unit Count
4
Defined Bond Stereocenter Count
3
EC Number
239-711-8
Exact Mass
493.12g/mol
H-Bond Acceptor
6
H-Bond Donor
3
Heavy Atom Count
22
Monoisotopic Mass
493.12g/mol
Rotatable Bond Count
3
Topological Polar Surface Area
112A^2
Application
Tris(2,4-pentanedionato)iridium(III), an orange-yellow crystalline powder, is primarily utilized for its versatility in various chemical and industrial applications. It is easily soluble in benzene and chloroform, which enhances its utility as a precursor in numerous synthesis processes, but it remains insoluble in water. This compound plays a crucial role as a photoreducing agent and a catalyst, particularly for the hydrogenation of sulfur-containing compounds. Its significance extends to organic synthesis where it aids in catalysis reactions, including the formation of carbon nanostructures, and serves as a precursor for heterogeneous catalysts across different supports, facilitating a range of catalytic applications like water oxidation and CO preferential oxidation. Furthermore, it is employed as a key material in the synthesis of phosphorescent iridium complexes with arylpyridine ligands. Tris(2,4-pentanedionato)iridium(III) is instrumental in chemical vapor deposition (CVD) and atomic layer deposition (ALD) to produce Ir and Ir2O3 films on various substrates. Additionally, its application using metal-organic chemical vapor deposition (MOCVD) technology allows for the creation of tomahawk coatings, pivotal in the production of base materials for engines in missiles, rockets, and automobiles. It also functions effectively as a deposition source for crafting Ir-C cluster films on ZrO2 substrates, known for their excellent electrochemical properties.
January 28, 2025

Exceptional Precursor for Advanced Catalysis

The Tris(2,4-pentanedionato)iridium(III) from Alfa Chemistry proved outstanding in our lab. It enabled efficient MOCVD coatings for missile engine bases and was a robust photoreducing agent in phenylpyridine solutions. Excellent solubility profile!

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