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Tris(N,N-bis(trimethylsilyl)amide)lanthanum(III), min. 98% (99.9%-La) (REO)

Catalog Number
ACM175923076
Product Name
Tris(N,N-bis(trimethylsilyl)amide)lanthanum(III), min. 98% (99.9%-La) (REO)
Structure
Tris(N,N-bis(trimethylsilyl)amide)lanthanum(III), min. 98% (99.9%-La) (REO)
CAS
175923-07-6
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Synonyms
Silanamine,1,1,1-trimethyl-N-(trimethylsilyl)-, lanthanum(3+) salt (3:1); Lanthanum tris[trimethyl-N-(trimethylsilyl)silanaminide]; 175923-07-6; LANTHANUM TRIS(HEXAMETHYLDISILAZIDE); bis(trimethylsilyl)azanide; AC1O1C9N; DTXSID30421941; Tris[bis(trimethylsilyl)amino] lanthanum;
IUPAC Name
bis(trimethylsilyl)azanide;lanthanum(3+);
Molecular Weight
620.066g/mol
Molecular Formula
C18H54LaN3Si6;
InChI
InChI=1S/3C6H18NSi2.La/c3*1-8(2,3)7-9(4,5)6;/h3*1-6H3;/q3*-1;+3;
InChI Key
ZDYNTRMQDURVDM-UHFFFAOYSA-N;
Complexity
76.2
Covalently-Bonded Unit Count
4
Exact Mass
619.2g/mol
H-Bond Acceptor
3
Heavy Atom Count
28
Monoisotopic Mass
619.2g/mol
Rotatable Bond Count
6
Topological Polar Surface Area
3A^2
Application
Catalyst precursor for enantioselective intramolecular hydroamination of aminoalkenes and aminodienes.

Catalyzes a mild and highly selective addition of terminal alkynes to nitriles to form conjugated ynones.

Catalytic amidation of aldehydes with amines.
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