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Tris(N,N-bis(trimethylsilyl)amide)lanthanum(III), min. 98% (99.9%-La) (REO)

Catalog Number
ACM175923076-3
Product Name
Tris(N,N-bis(trimethylsilyl)amide)lanthanum(III), min. 98% (99.9%-La) (REO)
Structure
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CAS
175923-07-6
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Synonyms
Silanamine,1,1,1-trimethyl-N-(trimethylsilyl)-, lanthanum(3+) salt (3:1); Lanthanum tris[trimethyl-N-(trimethylsilyl)silanaminide]; 175923-07-6; LANTHANUM TRIS(HEXAMETHYLDISILAZIDE); bis(trimethylsilyl)azanide; AC1O1C9N; DTXSID30421941; Tris[bis(trimethylsilyl)amino] lanthanum;
IUPAC Name
bis(trimethylsilyl)azanide;lanthanum(3+);
Molecular Weight
620.066g/mol
Molecular Formula
C18H54LaN3Si6;
Canonical SMILES
C[Si](C)(C)[N-][Si](C)(C)C.C[Si](C)(C)[N-][Si](C)(C)C.C[Si](C)(C)[N-][Si](C)(C)C.[La+3];
InChI
InChI=1S/3C6H18NSi2.La/c3*1-8(2,3)7-9(4,5)6;/h3*1-6H3;/q3*-1;+3;
InChI Key
ZDYNTRMQDURVDM-UHFFFAOYSA-N;
Complexity
76.2
Covalently-Bonded Unit Count
4
Exact Mass
619.2g/mol
H-Bond Acceptor
3
Heavy Atom Count
28
Monoisotopic Mass
619.2g/mol
Rotatable Bond Count
6
Topological Polar Surface Area
3A^2
Application
Tris(N,N-bis(trimethylsilyl)amide)lanthanum(III), min. 98% (99.9%-La) (REO), is designed to facilitate a range of catalytic processes, including the enantioselective intramolecular hydroamination of aminoalkenes and aminodienes. It effectively catalyzes the mild and highly selective addition of terminal alkynes to nitriles, yielding conjugated ynones, and is also employed in the catalytic amidation of aldehydes with amines, demonstrating its versatility and efficiency in various synthetic applications.
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