CAS 50525-27-4 Tris(2,2'-bipyridyl)dichlororuthenium(II) hexahydrate

Synonyms

SY010221; dichloride; Tris(2,2-bipyridyl)ruthenium(ii)chloride hexahydrate; Tris(2,2-bipyridyl)ruthenium(II) chloride hexahydrate; ruthenium(2+); 2,2'-BIPYRIDINE RUTHENOUS DICHLORIDE HEXAHYDRATE; TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II)CHLORIDEHEXAHYDRATE; Tris(2,2'-bipyridyl)ruthenium(II) chloride hexahydrate; Tris(2,2 inverted exclamation marka-bipyridine)dichlororuthenium(II) hexahydrate; Tris(2,2'-bipyridyl)ruthenium(II)Chloride hexahydrate;

IUPAC Name

2-pyridin-2-ylpyridine;ruthenium(2+);dichloride;hexahydrate;

Molecular Weight

748.624g/mol

Molecular Formula

C30H36Cl2N6O6Ru;

Canonical SMILES

C1=CC=NC(=C1)C2=CC=CC=N2.C1=CC=NC(=C1)C2=CC=CC=N2.C1=CC=NC(=C1)C2=CC=CC=N2.O.O.O.O.O.O.[Cl-].[Cl-].[Ru+2];

InChI

InChI=1S/3C10H8N2.2ClH.6H₂O.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;;;;;;;;;/h3*1-8H;2*1H;6*1H2;/q;;;;;;;;;;;+2/p-2;

InChI Key

WHELTKFSBJNBMQ-UHFFFAOYSA-L;

Complexity

120

Covalently-Bonded Unit Count

Exact Mass

748.112g/mol

H-Bond Acceptor

H-Bond Donor

Heavy Atom Count

Monoisotopic Mass

748.112g/mol

Rotatable Bond Count

Topological Polar Surface Area

83.3A^2

Application

Tris(2,2'-bipyridyl)dichlororuthenium(II) hexahydrate, appearing as a red to orange powder or crystals, serves primarily as an oxygen-sensitive fluorescent stain ideal for measuring oxygen concentration in microfluidic chips. This versatile compound functions as a catalyst in light-induced redox reactions and plays a crucial role in research on photochemical water splitting. Its applications extend across various domains, including photoelectrical chemical components, photovoltaic cells, smart biosensors, and pharmaceutical research. Moreover, as a metal complex, it operates as a luminescent dye, capable of being excited by visible light to form long-lived luminescent states, thereby finding use in electroluminescent devices.

January 24, 2025

Reliable Catalyst for Advanced Research

I used Alfa Chemistry's Tris(2,2'-bipyridyl)dichlororuthenium(II) hexahydrate in our lab for photo-induced redox reactions. It's crucial for studying photochemical water splitting-remarkable stability and performance. Highly recommend for photochemistry applications.