Molecular Weight
739.4
Molecular Formula
C20H15AuF6NO4PS2
Purity
0.99
Appearance
white to off-white powder
MDL Number
MFCD12911910
Symbol
GHS07
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- Triphenylphosphinegold(I) bis(trifluoromethanesulfonyl)imidate, min. 98%
Triphenylphosphinegold(I) bis(trifluoromethanesulfonyl)imidate, min. 98%
Catalog Number
ACM866395166-2
Product Name
Triphenylphosphinegold(I) bis(trifluoromethanesulfonyl)imidate, min. 98%
Structure
![{[CurrentData.Name]}](https://resource.alfachemic.com/structure/866395-16-6.gif)
CAS
866395-16-6
Application
Triphenylphosphinegold(I) bis(trifluoromethanesulfonyl)imidate, with a minimum purity of 98%, is a light purple powder functioning as a versatile coordination compound and catalyst in various chemical transformations. Its primary purpose is to promote the addition of nucleophiles to alleneamides, facilitating complex reactions such as the gold- and Brønsted acid-catalyzed cycloisomerization of 1,8-diynyl vinyl acetates to form bicycle[2.2.1]hept-2-en-7-ones. Additionally, it is employed in synthesizing spiro[piperidine-3,3'-oxindoles], conducting the gold(I)-catalyzed Rautenstrauch rearrangement, and achieving gold-catalyzed π-directed regioselective cyclization of bis(o-alkynyl benzyl alcohols) to rapidly access dihydroisobenzofuran derivatives. Furthermore, this compound supports acid-catalyzed cycloisomerization for the synthesis of diverse nitrogen-containing spiro heterocycles and acts as a catalyst in the domino synthesis of functionalized benzofurans and tetracyclic isochromans via formal carboalkoxylation.
February 7, 2025
Exceptional Catalyst for Complex Reactions
Using Triphenylphosphinegold(I) bis(trifluoromethanesulfonyl)imidate greatly enhanced our research efficiency. Its reliability in promoting nucleophile additions and facilitating complex cycloisomerizations was remarkable. A must-have for synthesis of diverse heterocycles and isochromans!
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