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(Triphenylphosphine)gold(I) Chloride
PRICE INQUIRYCatalog Number
ACM14243642-4
Product Name
(Triphenylphosphine)gold(I) Chloride
Structure
![{[CurrentData.Name]}](https://resource.alfachemic.com/structure/14243-64-2.gif)
CAS
14243-64-2
Synonyms
TRIPHENYLPHOSPHINEGOLD (I) CHLORIDE; A807907; SY009694; triphenylphosphane; Chloro(triphenylphosphine)gold(I), >=99.9% trace metals basis; SCHEMBL1450566; (PH3P)AUCL; Chloro(triphenylphosphine)gold(I), 99%; Chloro(triphenylphosphine)gold(I), Premion(R); MFCD00009588;
IUPAC Name
chlorogold;triphenylphosphane;
Molecular Weight
494.708g/mol
Molecular Formula
C18H15AuClP;
Canonical SMILES
C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Au];
InChI
InChI=1S/C18H15P.Au.ClH/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h1-15H;;1H/q;+1;/p-1;
InChI Key
IFPWCRBNZXUWGC-UHFFFAOYSA-M;
Storage
Store under Nitrogen
Complexity
204
Covalently-Bonded Unit Count
2
EC Number
238-117-6
Exact Mass
494.027g/mol
Heavy Atom Count
21
Monoisotopic Mass
494.027g/mol
Rotatable Bond Count
3
Topological Polar Surface Area
0A^2
Application
Triphenylphosphine gold(I) chloride serves as a vital reagent in gold chemistry, playing a crucial role in various organic synthesis processes. It effectively catalyzes rearrangement reactions and is instrumental in preparing 1-methylthyminato-N3-triphenylphosphinegold(I) through its reaction with 1-methylthymine. Additionally, this compound acts as a precursor for synthesizing both gold(I) and gold(III) organometallic compounds. Its capabilities extend to facilitating the cyclization of O-propargyl carbamates into alkylideneoxazolidinones via a 5-exo-dig pathway and promoting the cycloisomerization of enynes with cyclic olefins into complex polycyclic dienes, all at room temperature.
March 10, 2025
Exceptional Catalyst for Organic Synthesis
Triphenylphosphine gold(I) chloride is a superb reagent in my lab. Its efficiency in catalyzing rearrangement and cyclization reactions significantly aids our synthesis of complex compounds. Its reliability as a catalyst is truly impressive.
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