CAS 2622-14-2 Tricyclohexylphosphine - Catalysts / Alfa Chemistry

Synonyms

(Cy)3P; I14-4059; MFCD00003853; CTK1A6004; NSC 158657; CS-0020124; AKOS015840835; J-016328; KS-00000US7; tricydohexyl phosphine;

IUPAC Name

tricyclohexylphosphane;

Molecular Weight

280.436g/mol

Molecular Formula

C18H33P;

Canonical SMILES

C1CCC(CC1)P(C2CCCCC2)C3CCCCC3;

InChI

InChI=1S/C18H33P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h16-18H,1-15H2;

InChI Key

WLPUWLXVBWGYMZ-UHFFFAOYSA-N;

Storage

−20°C

Complexity

202

Covalently-Bonded Unit Count

EC Number

220-069-2

Exact Mass

280.232g/mol

Heavy Atom Count

Monoisotopic Mass

280.232g/mol

NSC Number

158657

Rotatable Bond Count

Topological Polar Surface Area

0A^2

MSDS

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COA

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Spec Sheet

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Application

Tricyclohexyl Phosphine is a ligand catalyst used primarily in organometallic chemistry.

Ligand used in the Pd-catalyzed coupling of malononitrile with aryl halides.

suzuki reaction: Bulky phosphine ligand used with a Pd(0)-triolefinic macrocycle catalyst for Suzuki coupling of aryl bromides and chlorides.

This ligand is applied with Ni as a key intermediate in the formation of cylcopentane compounds.

As a reagent, Tricyclohexylphosphine is used for a range of metal-catalyzed organic transformations.

Crabtree's catalyst is an organoiridium compound containing tricyclohexyl phosphine used for hydrogenation of mono-, di-, tri-, and tetra- substituted substrates and hydrogen transfer reactions.

Grubbs' catalysts consists of transition metal ruthenium and tricylohexyl phosphine utilized in olefin metathesis in synthetic organic chemistry.