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trans-Bis(acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II)

trans-Bis(acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II)

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Catalog Number

ACM172418325-2

Product Name

Structure

CAS

172418-32-5

Product Overview
Usage

Synonyms

HERRMANN'S PALLADACYCLE; I14-33199; trans-Di-|I-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium; CATACXIUM(R) C; Herrmann inverted exclamation markas palladacycle; trans-Bis(acetato)bis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium(II); AKOS015908997; trans-Bis(acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II); J-525029; Herrmann-Beller palladacycle;

IUPAC Name

acetic acid;(2-methanidylphenyl)-bis(2-methylphenyl)phosphane;palladium;

Molecular Weight

939.674g/mol

Molecular Formula

C46H48O4P2Pd2-2;

Canonical SMILES

CC1=CC=CC=C1P(C2=CC=CC=C2C)C3=CC=CC=C3[CH2-].CC1=CC=CC=C1P(C2=CC=CC=C2C)C3=CC=CC=C3[CH2-].CC(=O)O.CC(=O)O.[Pd].[Pd];

InChI

InChI=1S/2C21H20P.2C2H4O2.2Pd/c2*1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3;2*1-2(3)4;;/h2*4-15H,1H2,2-3H3;2*1H3,(H,3,4);;/q2*-1;;;;;

InChI Key

VWGJFGJEXBXEDJ-UHFFFAOYSA-N;

Complexity

409

Covalently-Bonded Unit Count

Exact Mass

940.11g/mol

Formal Charge

-2

H-Bond Acceptor

H-Bond Donor

Heavy Atom Count

Monoisotopic Mass

938.11g/mol

Rotatable Bond Count

Topological Polar Surface Area

74.6A^2

Application

Trans-Bis(acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II) is a versatile homogeneous catalyst primarily used to facilitate carbon-carbon and carbon-nitrogen bond formation in organic synthesis. It plays a crucial role in reactions such as Heck and Suzuki, as well as in the olefination of haloarenes, enhancing efficiency and selectivity in chemical transformations. Available as a yellow powder, this catalyst is offered in collaboration with Solvias AG, ensuring high-quality performance for various cross-coupling applications.

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