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Titanium(IV) bromide

Catalog Number
ACM7789686-2
Product Name
Titanium(IV) bromide
Structure
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CAS
7789-68-6
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Synonyms
7789-68-6;ACMC-1BK8L;CTK3J2898;AKOS015832999;RTR-024961;TR-024961;TITANIUM TETRABROMIDE (99.9% on metals basis);
IUPAC Name
titanium(4+);tetrabromide;
Molecular Weight
367.483g/mol
Molecular Formula
TiBr4;Br4Ti;
Canonical SMILES
[Ti+4].[Br-].[Br-].[Br-].[Br-];
InChI
InChI=1S/4BrH.Ti/h4*1H;/q;;;;+4/p-4;
InChI Key
UBZYKBZMAMTNKW-UHFFFAOYSA-J;
Covalently-Bonded Unit Count
5
Exact Mass
367.617g/mol
H-Bond Acceptor
4
Heavy Atom Count
5
Monoisotopic Mass
363.621g/mol
Topological Polar Surface Area
0A^2
UNII
1CBW950X1W
Application
Titanium(IV) bromide, which appears as orange, low-melting lumps and powder, serves as a Lewis acid catalyst in organic synthesis. It effectively reacts with tetrahydrofuran and 2-methylpyridine, forming adducts like TiBr4(THF)2 and TiBr4(2-MePy). Additionally, it plays a crucial role in creating titanium silicide thin films on silicon substrates.
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