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Tetrapropylammonium Perruthenate

Catalog Number
ACM114615826-2
Product Name
Tetrapropylammonium Perruthenate
Structure
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CAS
114615-82-6
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  • Usage
Synonyms
1-propanaminium, n,n,n-tripropyl-, t-4-tetraoxoruthenate 1-
IUPAC Name
ruthenium;tetrapropylazanium;hydroxide;trihydrate
Molecular Weight
351.43
Molecular Formula
C12H28NO4Ru
Canonical SMILES
CCC[N+](CCC)(CCC)CCC.O.O.O.[OH-].[Ru]
InChI
InChI=1S/C12H28N.4H₂O.Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;;;;;/h5-12H2,1-4H3;4*1H2;/q+1;;;;;/p-1;
InChI Key
HUCLFLGLPCVDMZ-UHFFFAOYSA-M
Melting Point
160.0°C
Appearance
Black Powder
Complexity
80.2
Covalently-Bonded Unit Count
6
Exact Mass
359.161g/mol
H-Bond Acceptor
4
H-Bond Donor
4
Heavy Atom Count
18
Monoisotopic Mass
359.161g/mol
Rotatable Bond Count
8
Topological Polar Surface Area
4A^2
Application
Tetrapropylammonium Perruthenate is a dark green solid that serves as a mild oxidizing agent designed for the selective transformation of alcohols into their corresponding carbonyl compounds, specifically converting primary alcohols to aldehydes and secondary alcohols to ketones. This reagent is distinguished by its non-volatile, air-stable nature, and solubility, allowing it to be used in various oxidation reactions either in stoichiometric amounts or catalytically when paired with a suitable co-oxidant. Furthermore, Tetrapropylammonium Perruthenate offers promise for sustainable practices in chemical processes, including potential applications in chemical recycling.
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