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tert-Butyldiisopropylphosphine

Catalog Number
ACM51567056-1
Product Name
tert-Butyldiisopropylphosphine
CAS
51567-05-6
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Synonyms
ZINC71771890; MFCD06200720; AC1LBBS1; tert-Butyl(diisopropyl)phosphine; di-isopropyl-t-butylphosphane; 51567-05-6; SCHEMBL984937; tert-butyl-di(propan-2-yl)phosphane; tert-Butyldiisopropylphosphane; tert-Butyldiisopropylphosphine, 97%;
IUPAC Name
tert-butyl-di(propan-2-yl)phosphane;
Molecular Weight
174.268g/mol
Molecular Formula
C10H23P;
Canonical SMILES
CC(C)P(C(C)C)C(C)(C)C;
InChI
InChI=1S/C10H23P/c1-8(2)11(9(3)4)10(5,6)7/h8-9H,1-7H3;
InChI Key
OLSMQSZDUXXYAY-UHFFFAOYSA-N;
Complexity
101
Covalently-Bonded Unit Count
1
Exact Mass
174.154g/mol
Heavy Atom Count
11
Monoisotopic Mass
174.154g/mol
Rotatable Bond Count
3
Topological Polar Surface Area
0A^2
Application
Tert-Butyldiisopropylphosphine serves as an effective monodentate phosphine ligand designed to enhance catalytic processes, specifically the selective dimerization of propylene into dimethylbutenes. This unique ligand not only aids in this transformation but also plays a crucial role in facilitating the formation of ethylene glycol from synthesis gas when used in conjunction with rhodium as a catalyst. Furthermore, it contributes to the process by moderating the electronic effects, optimizing conditions for the efficient production of ethylene glycol.
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